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Enzyme-Controlled Nitrogen-Atom Transfer Enables Regiodivergent C–H Amination
[Image: see text] We recently demonstrated that variants of cytochrome P450(BM3) (CYP102A1) catalyze the insertion of nitrogen species into benzylic C–H bonds to form new C–N bonds. An outstanding challenge in the field of C–H amination is catalyst-controlled regioselectivity. Here, we report two en...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American Chemical
Society
2014
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| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4227740/ https://ncbi.nlm.nih.gov/pubmed/25325618 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja509308v |
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