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Enzyme-Controlled Nitrogen-Atom Transfer Enables Regiodivergent C–H Amination
[Image: see text] We recently demonstrated that variants of cytochrome P450(BM3) (CYP102A1) catalyze the insertion of nitrogen species into benzylic C–H bonds to form new C–N bonds. An outstanding challenge in the field of C–H amination is catalyst-controlled regioselectivity. Here, we report two en...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4227740/ https://ncbi.nlm.nih.gov/pubmed/25325618 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja509308v |
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