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Enantioselective Enzyme-Catalyzed Aziridination Enabled by Active-Site Evolution of a Cytochrome P450

[Image: see text] One of the greatest challenges in protein design is creating new enzymes, something evolution does all the time, starting from existing ones. Borrowing from nature’s evolutionary strategy, we have engineered a bacterial cytochrome P450 to catalyze highly enantioselective intermolec...

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Bibliographic Details
Published in:ACS Cent Sci
Main Authors: Farwell, Christopher C., Zhang, Ruijie K., McIntosh, John A., Hyster, Todd K., Arnold, Frances H.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2015
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4571169/
https://ncbi.nlm.nih.gov/pubmed/26405689
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.5b00056
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