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Asymmetric Enzymatic Synthesis of Allylic Amines:A Sigmatropic Rearrangement Strategy
Sigmatropic rearrangements, while rare in biology, offer opportunities for the efficient and selective synthesis of complex chemical motifs. A “P411” serine-ligated variant of cytochrome P450(BM3) has been engineered to initiate a sulfimidation/[2,3]-sigmatropic rearrangement sequence in whole E. co...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4818679/ https://ncbi.nlm.nih.gov/pubmed/26970325 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201601056 |
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