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Leveraging the Micellar Effect: Gold-Catalyzed Dehydrative Cyclizations … in Water at Room Temperature

[Image: see text] The first examples of gold-catalyzed cyclizations of diols and triols to the corresponding hetero- or spirocycles in a bulk aqueous medium are presented. These reactions take place within nanomicelles, where the hydrophobic effect is operating, thereby driving the dehydrations, not...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Minkler, Stefan R. K., Isley, Nicholas A., Lippincott, Daniel J., Krause, Norbert, Lipshutz, Bruce H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4219360/
https://ncbi.nlm.nih.gov/pubmed/24433154
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol403402h
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