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Ultraefficient homogeneous catalyst for the CO(2)-to-CO electrochemical conversion

A very efficient electrogenerated Fe(0) porphyrin catalyst was obtained by substituting in tetraphenylporphyrin two of the opposite phenyl rings by ortho-, ortho'-phenol groups while the other two are perfluorinated. It proves to be an excellent catalyst of the CO(2)-to-CO conversion as to sele...

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Bibliographic Details
Main Authors: Costentin, Cyrille, Passard, Guillaume, Robert, Marc, Savéant, Jean-Michel
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2014
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4210317/
https://ncbi.nlm.nih.gov/pubmed/25288744
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1416697111
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