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Efficient and selective molecular catalyst for the CO(2)-to-CO electrochemical conversion in water

Substitution of the four paraphenyl hydrogens of iron tetraphenylporphyrin by trimethylammonio groups provides a water-soluble molecule able to catalyze the electrochemical conversion of carbon dioxide into carbon monoxide. The reaction, performed in pH-neutral water, forms quasi-exclusively carbon...

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Pubblicato in:Proc Natl Acad Sci U S A
Autori principali: Costentin, Cyrille, Robert, Marc, Savéant, Jean-Michel, Tatin, Arnaud
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4460501/
https://ncbi.nlm.nih.gov/pubmed/26038542
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1507063112
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