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syn-1,2-Carboboration of Alkynes with Borenium Cations
The reaction of 8-(trimethylsiloxy)quinoline (QOTMS) with BCl(3) and (aryl)BCl(2) forms QOBCl(2) and QOBCl(aryl). The subsequent addition of stoichiometric AlCl(3) follows one of two paths, dependent on the steric demands of the QO ligand and the electrophilicity of the resulting borenium cation. Th...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
WILEY-VCH Verlag
2014
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4209141/ https://ncbi.nlm.nih.gov/pubmed/25138585 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201403614 |
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