Facile Arylation of Four-Coordinate Boron Halides by Borenium Cation Mediated Boro-desilylation and -destannylation

[Image: see text] The addition of AlCl(3) to four-coordinate boranes of the general formula (C–N-chelate)BCl(2) results in halide abstraction and formation of three-coordinate borenium cations of the general formula [(C–N-chelate)BCl](+). The latter react with both arylstannanes and arylsilanes by b...

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Bibliografske podrobnosti
izdano v:Organometallics
Main Authors: Crossley, Daniel L., Cid, Jessica, Curless, Liam D., Turner, Michael L., Ingleson, Michael J.
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2015
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4819459/
https://ncbi.nlm.nih.gov/pubmed/27064894
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.5b00857
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