A carregar...
Highly selective catalytic trans-hydroboration of alkynes mediated by borenium cations and B(C(6)F(5))(3)
The trans-hydroboration of terminal alkynes mediated by borenium cations [NHC(9-BBN)](+) (NHC = N-heterocyclic carbene, 9-BBN = 9-borabicyclo(3.3.1)nonane) exclusively affords Z-vinylboranes. NHCs and chelating dialkyl substituents on the borenium cation and “non”-basic anions were essential to prec...
Na minha lista:
| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6006955/ https://ncbi.nlm.nih.gov/pubmed/29997833 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04798f |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|