trans-Hydroboration–oxidation products in Δ(5)-steroids via a hydroboration-retro-hydroboration mechanism

Herein, we report for the first time a “trans-hydroboration–oxidation product” isolated and characterized under traditional hydroboration–oxidation conditions using cholesterol and diosgenin as substrates. These substrates are excellent starting materials because of the rigidity and different struct...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Hilario-Martínez, J. Ciciolil, Murillo, Fernando, García-Méndez, Jair, Dzib, Eugenia, Sandoval-Ramírez, Jesús, Muñoz-Hernández, Miguel Ángel, Bernès, Sylvain, Kürti, László, Duarte, Fernanda, Merino, Gabriel, Fernández-Herrera, María A.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162471/
https://ncbi.nlm.nih.gov/pubmed/34094471
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01701a
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