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Total Synthesis of (−)-N-Methylwelwitindolinone B Isothiocyanate via a Chlorinative Oxabicycle Ring-Opening Strategy

[Image: see text] The first total synthesis of N-methylwelwitindolinone B isothiocyanate is reported. The route features several key steps, including a regio- and diastereoselective chlorinative oxabicycle ring-opening reaction to introduce the challenging alkyl chloride motif.

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Detalhes bibliográficos
Main Authors: Weires, Nicholas A., Styduhar, Evan D., Baker, Emma L., Garg, Neil K.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4206695/
https://ncbi.nlm.nih.gov/pubmed/25275668
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5087672
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