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Total Synthesis of Oxidized Welwitindolinones and (–)-N-Methylwelwitindolinone C Isonitrile

We report the total synthesis of (–)-Nmethylwelwitindolinone C isonitrile, in addition to the total syntheses of the 3-hydroxylated welwitindolinones. Our routes to these elusive natural products feature the strategic use of a deuterium kinetic isotope effect to improve the efficiency of a late-stag...

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Detalhes bibliográficos
Main Authors: Quasdorf, Kyle W., Huters, Alexander D., Lodewyk, Michael W., Tantillo, Dean J., Garg, Neil K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3266994/
https://ncbi.nlm.nih.gov/pubmed/22235964
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja210837b
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