Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the Cu(I)/Cu(III) Manifold in Copper Catalysis

[Image: see text] A combination of experimental and density functional theory (DFT) investigations suggests that the Cu-catalyzed fluorination of unsymmetrical diaryliodonium salts with general structure [Mes(Ar)I](+) in N,N′-dimethylformamide proceeds through a Cu(I)/Cu(III) catalytic cycle. A low...

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Egile Nagusiak: Ichiishi, Naoko, Canty, Allan J., Yates, Brian F., Sanford, Melanie S.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: American Chemical Society 2014
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4195515/
https://ncbi.nlm.nih.gov/pubmed/25328272
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om5007903
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