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Combining Transition Metal Catalysis with Radical Chemistry: Dramatic Acceleration of Palladium-Catalyzed C–H Arylation with Diaryliodonium Salts

This paper describes a photoredox palladium/iridium-catalyzed C–H arylation with diaryliodonium reagents. Details of the reaction optimization, substrate scope, and mechanism are presented along with a comparison to a related method in which aryldiazonium salts are used in place of diaryliodonium re...

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Bibliographic Details
Main Authors: Neufeldt, Sharon R., Sanford, Melanie S.
Format: Artigo
Language:Inglês
Published: 2012
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3740597/
https://ncbi.nlm.nih.gov/pubmed/23950736
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201200738
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