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Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the Cu(I)/Cu(III) Manifold in Copper Catalysis
[Image: see text] A combination of experimental and density functional theory (DFT) investigations suggests that the Cu-catalyzed fluorination of unsymmetrical diaryliodonium salts with general structure [Mes(Ar)I](+) in N,N′-dimethylformamide proceeds through a Cu(I)/Cu(III) catalytic cycle. A low...
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| Main Authors: | , , , |
|---|---|
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American
Chemical Society
2014
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| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4195515/ https://ncbi.nlm.nih.gov/pubmed/25328272 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om5007903 |
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