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Catalytic Asymmetric α-Iminol Rearrangement: New Chiral Platforms

[Image: see text] A series of 19 different asymmetric catalysts were screened in an effort to identify the first chiral catalyst for the rearrangement of α-hydroxy imines to α-amino ketones involving a 1,2-carbon shift. Although aluminate complexes of VAPOL, VANOL, and 7,7′-(t)Bu(2)VANOL were quite...

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Hlavní autoři: Zhang, Xin, Staples, Richard J., Rheingold, Arnold L, Wulff, William D.
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2014
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4195388/
https://ncbi.nlm.nih.gov/pubmed/25247674
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5065685
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