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Regioselectivity of Diels-Alder Reactions Between 6,7-Dehydrobenzofuran and 2-Substituted Furans

We describe the first report of the generation of 6,7-dehydrobenzofuran (6,7-benzofuranyne) from 6,7-dihalobenzofurans via metal-halogen exchange and elimination, in a manner similar to our previous work with 6,7-indole arynes. This benzofuranyne undergoes highly regioselective Diels-Alder cycloaddi...

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Detalhes bibliográficos
Main Authors: Brown, Neil, Buszek, Keith R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4179875/
https://ncbi.nlm.nih.gov/pubmed/25278635
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2012.05.118
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