Experimental and Theoretical Investigations into the Unusual Regioselectivity of 4,5-, 5,6-, and 6,7-Indole Aryne Cycloadditions

[Image: see text] The 6,7-indolyne shows remarkable regioselectivity in its cycloaddition with 2-substituted furans. Electron-donating groups give predominantly the more sterically crowded product, while electron-withdrawing groups display the opposite regioselectivity. By contrast, 4,5- and 5,6-ind...

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Hauptverfasser: Garr, Ashley N., Luo, Diheng, Brown, Neil, Cramer, Christopher J., Buszek, Keith R., VanderVelde, David
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2010
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4175992/
https://ncbi.nlm.nih.gov/pubmed/19961152
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol902415s
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