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Anion-Dependent Switch in C–X Reductive Elimination Diastereoselectivity

[Image: see text] Reaction of a complex Pt organometallic species with electrophilic halogen sources in the presence of X(–) ligands changes the mechanism of reductive elimination from a concerted reductive coupling type to an S(N)2 type reductive elimination. In the absence of the added X(–) ligand...

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Bibliografske podrobnosti
Main Authors: Geier, Michael J., Dadkhah Aseman, Marzieh, Gagné, Michel R.
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2014
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4157736/
https://ncbi.nlm.nih.gov/pubmed/25221379
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om5006929
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