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Promoting C–C Bond Coupling of Benzyne and Methyl Ligands in Electron-Deficient (triphos)Pt–CH(3)(+) Complexes
[Image: see text] In situ generated benzyne reacts at room temperature with (triphos)Pt–CH(3)(+) to form a five-coordinate π-complex (2) that is isolable and stable in solution. Thermolysis of 2 at 60 °C generates (triphos)Pt(o-tolyl)(+) (3), which is the product of formal migratory insertion of CH(...
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| Publicado no: | Organometallics |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2015
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4480611/ https://ncbi.nlm.nih.gov/pubmed/26146438 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.5b00121 |
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