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Promoting C–C Bond Coupling of Benzyne and Methyl Ligands in Electron-Deficient (triphos)Pt–CH(3)(+) Complexes

[Image: see text] In situ generated benzyne reacts at room temperature with (triphos)Pt–CH(3)(+) to form a five-coordinate π-complex (2) that is isolable and stable in solution. Thermolysis of 2 at 60 °C generates (triphos)Pt(o-tolyl)(+) (3), which is the product of formal migratory insertion of CH(...

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Detalhes bibliográficos
Publicado no:Organometallics
Main Authors: Aseman, Marzieh Dadkhah, Roselli, Christina A., Gagné, Michel R.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2015
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4480611/
https://ncbi.nlm.nih.gov/pubmed/26146438
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.5b00121
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