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An Enantiospecific Synthesis of Jiadifenolide()
A Robinson annulation, van Leusen homologation, and a desymmetrizing C–H oxidation enabled an enantiospecific synthesis of the neurotrophic natural product jiadifenolide. From a pulegone-derived building block, a key propellane intermediate was constructed through the use of simple reagents in a hig...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4153357/ https://ncbi.nlm.nih.gov/pubmed/24757120 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201402335 |
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