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Orthogonal dual thiol–chloroacetyl and thiol–ene couplings for the sequential one-pot assembly of heteroglycoclusters

We describe the first one-pot orthogonal strategy to prepare well-defined cyclopeptide-based heteroglycoclusters (hGCs) from glycosyl thiols. Both thiol–chloroactetyl coupling (TCC) and thiol–ene coupling (TEC) have been used to decorate cyclopeptides regioselectively with diverse combination of sug...

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Hlavní autoři: Fiore, Michele, Daskhan, Gour Chand, Thomas, Baptiste, Renaudet, Olivier
Médium: Artigo
Jazyk:Inglês
Vydáno: Beilstein-Institut 2014
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4142873/
https://ncbi.nlm.nih.gov/pubmed/25161711
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.160
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