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Stereoselective Synthesis of Cytotoxic Anhydrophytosphingosine Pachastrissamine (Jaspine B) from D-Xylose

[Image: see text] The first naturally occurring anhydrophytosphingosine, pachastrissamine (jaspine B), a marine compound cytotoxic toward P388, A549, HT29, and MEL28 cell lines at IC(50) = 0.01 μg/mL level, has been stereoselectively synthesized from D-xylose in 10 linear steps with 25.7% overall yi...

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Autores principales: Du, Yuguo, Liu, Jun, Linhardt, Robert J.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2006
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4140561/
https://ncbi.nlm.nih.gov/pubmed/16438548
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo051644y
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