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Mechanistic Insight with HBCH(2)CoA as a Probe to Polyhydroxybutyrate (PHB) Synthases
[Image: see text] Polyhydroxybutyrate (PHB) synthases catalyze the polymerization of 3-(R)-hydroxybutyrate coenzyme A (HBCoA) to produce polyoxoesters of 1–2 MDa. A substrate analogue HBCH(2)CoA, in which the S in HBCoA is replaced with a CH(2) group, was synthesized in 13 steps using a chemoenzymat...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4136709/ https://ncbi.nlm.nih.gov/pubmed/24896226 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cb5002735 |
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