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Differentiation of Histidine Tautomeric States using (15)N Selectively Filtered (13)C Solid-State NMR Spectroscopy

The histidine imidazole ring in proteins usually contains a mixture of three possible tautomeric states (two neutral - τ and π states and a charged state) at physiological pHs. Differentiating the tautomeric states is critical for understanding how the histidine residue participates in many structur...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Miao, Yimin, Cross, Timothy A., Fu, Riqiang
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2014
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4136442/
https://ncbi.nlm.nih.gov/pubmed/25026459
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jmr.2014.06.005
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