Characterization of a Paramagnetic Mononuclear Nonheme Iron-Superoxo Complex

[Image: see text] O(2) bubbling into a THF solution of Fe(II)(BDPP) (1) at −80 °C generates a reversible bright yellow adduct 2. Characterization by resonance Raman and Mössbauer spectroscopy provides complementary insights into the nature of 2. The former shows a resonance-enhanced vibration at 112...

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Hauptverfasser: Chiang, Chien-Wei, Kleespies, Scott T., Stout, Heather D., Meier, Katlyn K., Li, Po-Yi, Bominaar, Emile L., Que, Lawrence, Münck, Eckard, Lee, Way-Zen
Format: Artigo
Sprache:Inglês
Veröffentlicht: American Chemical Society 2014
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4132977/
https://ncbi.nlm.nih.gov/pubmed/25036460
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja504410s
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