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Divergent Outcomes of Carbene Transfer Reactions from Dirhodium- and Copper-Based Catalysts Separately or in Combination
The use of copper and rhodium catalysts separately and in combination directs reactions between vinyldiazoacetates 3 and cinnamaldehydes 2 to from formal [4+3]-cycloaddition (epoxidation followed by Cope rearrangement), intramolecular cyclopropanation, and Mukaiyama-aldol reactions selectively and i...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2011
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4128416/ https://ncbi.nlm.nih.gov/pubmed/25097911 |
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