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Improving the Stability and Catalyst Lifetime of the Halogenase RebH Using Directed Evolution

We previously reported that the halogenase RebH catalyzes selective halogenation of several heterocycles and carbocycles, but product yields were limited by enzyme instability. Here, we use directed evolution to engineer a RebH variant, 3-LR, with a T(opt) over 5 °C higher than that of wild type, an...

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Autores principales: Poor, Catherine B., Andorfer, Mary C., Lewis, Jared C.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2014
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4124618/
https://ncbi.nlm.nih.gov/pubmed/24849696
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cbic.201300780
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