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Regioselective Hydroacylation of 1,3-Dienes by Cobalt Catalysis

[Image: see text] We describe a cobalt-catalyzed hydroacylation of 1,3-dienes with non-chelating aldehydes. Aromatic aldehydes provide 1,4-addition products as the major isomer, while aliphatic aldehydes favor 1,2-hydroacylation products. The kinetic profile supports an oxidative cyclization mechani...

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Main Authors: Chen, Qing-An, Kim, Daniel K., Dong, Vy M.
格式: Artigo
語言:Inglês
出版: American Chemical Society 2014
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4117386/
https://ncbi.nlm.nih.gov/pubmed/24588202
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja500268w
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