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Synthetic studies on lemonomycin: construction of the tetracyclic core
A substrate-induced stereocontrol strategy was used to gain access to the tetracyclic core of (-)-lemonomycin. An advanced intermediate was prepared from a known substituted tyrosinol through a 16-step sequence, which involved a Pictet-Spengler reaction, a [3+2] dipolar cycloaddition and an enamide...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4114395/ https://ncbi.nlm.nih.gov/pubmed/25083002 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2013.05.009 |
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