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Bond angles in transition metal tetracarbonyl compounds: A further test of the theory of hybrid bond orbitals

An equation for the bond angles OC—M—CO for tetracarbonyl groups in which the transition metal atom M is enneacovalent, derived from the simple theory of hybrid sp(3)d(5) bond orbitals, is tested by comparison of the calculated values of the angles with the experimental values reported for many comp...

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Bibliographic Details
Main Author: Pauling, Linus
Format: Artigo
Language:Inglês
Published: 1978
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC411296/
https://ncbi.nlm.nih.gov/pubmed/16592490
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