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Bond angles in transition metal tetracarbonyl compounds: A further test of the theory of hybrid bond orbitals

An equation for the bond angles OC—M—CO for tetracarbonyl groups in which the transition metal atom M is enneacovalent, derived from the simple theory of hybrid sp(3)d(5) bond orbitals, is tested by comparison of the calculated values of the angles with the experimental values reported for many comp...

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Publicat a:Proc Natl Acad Sci U S A
Autor principal: Pauling, Linus
Format: Artigo
Idioma:Inglês
Publicat: National Academy of Sciences 1978
Matèries:
Accés en línia:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC411296/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592490/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.75.2.569
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