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Structure of transition-metal cluster compounds: Use of an additional orbital resulting from the f, g character of spd bond orbitals
A general theory of the structure of complexes of the transition metals is developed on the basis of the enneacovalence of the metals and the requirements of the electroneutrality principle. An extra orbital may be provided through the small but not negligible amount of f and g character of spd bond...
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| Format: | Artigo |
| Jezik: | Inglês |
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1977
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC431661/ https://ncbi.nlm.nih.gov/pubmed/16592470 |
| Oznake: |
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