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Isotopic ((18)O) shift in (31)P nuclear magnetic resonance applied to a study of enzyme-catalyzed phosphate—phosphate exchange and phosphate (oxygen)—water exchange reactions
An isotopic shift of the (31)P nuclear magnetic resonance due to (18)O bonded to phosphorus of 0.0206 ppm has been observed in inorganic orthophosphate and adenine nucleotides. Thus, the separation between the resonances of (31)P(18)O(4) and (31)P(16)O(4) at 145.7 MHz is 12 Hz and, in a randomized s...
Bewaard in:
| Gepubliceerd in: | Proc Natl Acad Sci U S A |
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| Hoofdauteurs: | , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
National Academy of Sciences
1978
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC411213/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/203929/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.75.1.200 |
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