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Isotopic ((18)O) shift in (31)P nuclear magnetic resonance applied to a study of enzyme-catalyzed phosphate—phosphate exchange and phosphate (oxygen)—water exchange reactions

An isotopic shift of the (31)P nuclear magnetic resonance due to (18)O bonded to phosphorus of 0.0206 ppm has been observed in inorganic orthophosphate and adenine nucleotides. Thus, the separation between the resonances of (31)P(18)O(4) and (31)P(16)O(4) at 145.7 MHz is 12 Hz and, in a randomized s...

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Vydáno v:Proc Natl Acad Sci U S A
Hlavní autoři: Cohn, Mildred, Hu, Angela
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 1978
Témata:
On-line přístup:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC411213/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/203929/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.75.1.200
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