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Isotopic ((18)O) shift in (31)P nuclear magnetic resonance applied to a study of enzyme-catalyzed phosphate—phosphate exchange and phosphate (oxygen)—water exchange reactions

An isotopic shift of the (31)P nuclear magnetic resonance due to (18)O bonded to phosphorus of 0.0206 ppm has been observed in inorganic orthophosphate and adenine nucleotides. Thus, the separation between the resonances of (31)P(18)O(4) and (31)P(16)O(4) at 145.7 MHz is 12 Hz and, in a randomized s...

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書誌詳細
出版年:Proc Natl Acad Sci U S A
主要な著者: Cohn, Mildred, Hu, Angela
フォーマット: Artigo
言語:Inglês
出版事項: National Academy of Sciences 1978
主題:
オンライン・アクセス:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC411213/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/203929/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.75.1.200
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