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Silane/iodine-based cleavage of esters and ethers under neutral conditions
New, efficient cleavage of carboxylic esters with iodotrimethylsilane or a mixture of phenyltrimethylsilane and iodine is described. Essentially neutral conditions can be maintained throughout the reactions. Ethers can be dealkylated by the latter method in high yields. The mechanism of the cleavage...
保存先:
| 主要な著者: | , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
1978
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC411170/ https://ncbi.nlm.nih.gov/pubmed/16592482 |
| タグ: |
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