Synthesis of Glycosyl Chlorides and Bromides by Chelation Assisted Activation of Picolinic Esters under Mild Neutral Conditions

A general method has been developed for the formation of glycosyl chlorides and bromides from picolinic esters under mild and neutral conditions. Benchtop stable picolinic esters are activated by a copper (II) halide species to afford the corresponding products in high yields with a traceless leavin...

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Publié dans:Org Lett
Auteurs principaux: Wen, Peng, Simmons, Christopher J., Ma, Zhi-xiong, Blaszczyk, Stephanie A., Balzer, Paul G., Ye, Wenjing, Duan, Xiyan, Wang, Hao-Yuan, Yin, Dan, Stevens, Christopher M., Tang, Weiping
Format: Artigo
Langue:Inglês
Publié: 2020
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Article
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7050992/
https://ncbi.nlm.nih.gov/pubmed/32026682
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c00078
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