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Biomimetic Aerobic C–H Olefination of Cyclic Enaminones at Room Temperature: Development toward the Synthesis of 1,3,5-Trisubstituted Benzenes

A green and mild protocol for the dehydrogenative olefination of cyclic enaminones was devised via palladium catalysis at room temperature using oxygen as the terminal oxidant. The synthetic utility of the olefinated cyclic enaminones afforded a series of unique 1,3,5-trisubstituted benzenes via an...

詳細記述

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書誌詳細
主要な著者: Yu, Yi-Yun, Georg, Gunda I.
フォーマット: Artigo
言語:Inglês
出版事項: 2014
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC4111264/
https://ncbi.nlm.nih.gov/pubmed/25071423
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201300904
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