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Biomimetic Aerobic C–H Olefination of Cyclic Enaminones at Room Temperature: Development toward the Synthesis of 1,3,5-Trisubstituted Benzenes

A green and mild protocol for the dehydrogenative olefination of cyclic enaminones was devised via palladium catalysis at room temperature using oxygen as the terminal oxidant. The synthetic utility of the olefinated cyclic enaminones afforded a series of unique 1,3,5-trisubstituted benzenes via an...

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Autori principali: Yu, Yi-Yun, Georg, Gunda I.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2014
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4111264/
https://ncbi.nlm.nih.gov/pubmed/25071423
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201300904
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