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Boron–Heck Reaction of Cyclic Enaminones: Regioselective Direct Arylation via Oxidative Palladium(II) Catalysis

[Image: see text] An oxidative boron–Heck reaction of cyclic enaminones with arylboronic acids is reported. This protocol provides a regioselective arylation at the C6 position of cyclic enaminones. When an N-carbamylated cyclic enaminone was employed, a switch to a conjugate addition reaction occur...

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Bibliographic Details
Main Authors: Kim, Yong Wook, Georg, Gunda I.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2014
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3993847/
https://ncbi.nlm.nih.gov/pubmed/24650204
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol500105d
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