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Influence of Catalyst Structure and Reaction Conditions on Anti- vs. Syn-Aminopalladation Pathways in Pd-Catalyzed Alkene Carboamination Reactions of N-Allyl Sulfamides

The Pd-catalyzed coupling of N-allyl sulfamides with aryl and alkenyl triflates to afford cyclic sulfamide products is described. In contrast to other known Pd-catalyzed alkene carboamination reactions, these transformations may be selectively induced to occur by way of either anti- or syn-aminopall...

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Detalhes bibliográficos
Main Authors: Fornwald, Ryan M., Fritz, Jonathan A., Wolfe, John P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4102893/
https://ncbi.nlm.nih.gov/pubmed/24938206
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201402258
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