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Asymmetric Palladium-Catalyzed Alkene Carboamination Reactions for the Synthesis Of Cyclic Sulfamides
The synthesis of cyclic sulfamides via enantioselective Pd-catalyzed alkene carboamination reactions between N-allyl sulfamides and aryl or alkenyl bromides is described. High levels of asymmetric induction (up to 95:5 er) are achieved using a catalyst composed of Pd(2)(dba)(3) and (S)-Siphos-PE. De...
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| Publicado en: | Chemistry |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2016
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4932835/ https://ncbi.nlm.nih.gov/pubmed/26968748 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201600887 |
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