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Palladium-catalyzed alkene carboamination reactions for the synthesis of substituted piperazines

A strategy for the stereoselective preparation of enantiomerically enriched cis-2,6-disubstituted piperazines from amino acid precursors is described. The target compounds are generated in 95–99% ee with good to excellent levels of diastereoselectivity (usually 14:1 to >20:1) using Pd-catalyzed c...

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Autors principals: Nakhla, Josephine S., Schultz, Danielle M., Wolfe, John P.
Format: Artigo
Idioma:Inglês
Publicat: 2009
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2902800/
https://ncbi.nlm.nih.gov/pubmed/20640043
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2009.04.017
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