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Alkyl Isocyanides Serve as Transition State Analogs for Ligand Entry and Exit in Myoglobin()
Alkyl isocyanides (CNRs) identify pathways for diatomic ligand movement into and out of Mb, with their side chains acting as transition state analogs. The bound alkyl groups point either into the back of the distal pocket (in conformation, ν(CN) ≈ 2070–2090 cm(−1)), which allows hydrogen bond donati...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4102008/ https://ncbi.nlm.nih.gov/pubmed/20476741 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi1001745 |
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