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Straight-Chain Alkyl Isocyanides Open the Distal Histidine Gate in Crystal Structures of Myoglobin()

Crystal structures of methyl, ethyl, propyl and butyl isocyanide bound to sperm whale myoglobin (Mb) reveal two major conformations. In the in conformer, His(E7) is in a “closed” position, forcing the ligand alkyl chain to point inward. In the out conformer, His(E7) is in an “open” position, allowin...

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Auteurs principaux: Smith, Rober D., Blouin, George C., Johnson, Kenneth A., Phillips, George N., Olson, John S.
Format: Artigo
Langue:Inglês
Publié: 2010
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4074459/
https://ncbi.nlm.nih.gov/pubmed/20481504
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi1001739
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