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Expanding the Horizon of Intermolecular Trapping of In-Situ Generated α-Oxo Gold Carbenes: Efficient Oxidative Union of Allylic Sulfides and Terminal Alkynes via C-C Bond Formation
With a new P,S-bidentate phosphine as ligand to gold(I), the α-oxo gold carbenes generated in situ via gold-catalyzed intermolecular oxidation of terminal alkynes were effectively trapped by various allylic sulfides, resulting in the formation of α-aryl(alkyl)thio-γ.δ-unsaturated ketones upon facile...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2014
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4090113/ https://ncbi.nlm.nih.gov/pubmed/24622909 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4cc00739e |
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