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Oxidative Heck Vinylation for the Synthesis of Complex Dienes and Polyenes
We introduce an oxidative Heck reaction for selective complex diene and polyene formation. The reaction proceeds via oxidative Pd(II)/sulfoxide catalysis that retards palladiumhydride isomerizations which previously limited the Heck manifold’s capacity for furnishing stereodefined conjugated dienes....
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2013
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4084759/ https://ncbi.nlm.nih.gov/pubmed/23701421 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402891m |
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