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Preparation of Vinyl Silyl Ethers and Disiloxanes via the Silyl-Heck Reaction of Silyl Ditriflates

Vinyl silyl ethers and disiloxanes can now be prepared from aryl-substituted alkenes and related substrates using a silyl-Heck reaction. The reaction employs a commercially available catalyst system and mild conditions. This work represents a highly practical means of accessing diverse classes of vi...

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Hlavní autoři: Martin, Sara E. S., Watson, Donald A.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3816510/
https://ncbi.nlm.nih.gov/pubmed/23984876
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja407748z
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