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Total Synthesis of GEX1Q1, Assignment of C-5 Stereoconfiguration and Evaluation of Spliceosome Inhibitory Activity

[Image: see text] An enantioselective total synthesis of GEX1Q1 has been accomplished in a convergent manner. The C-5 asymmetric center has now been assigned through synthesis. GEX1Q1 displayed slightly better spliceosome inhibitory activity over its C-5 epimer. The salient features of this synthesi...

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Detalhes bibliográficos
Main Authors: Ghosh, Arun K., Ma, Nianchun, Effenberger, Kerstin A., Jurica, Melissa S.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4051430/
https://ncbi.nlm.nih.gov/pubmed/24869489
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol501345d
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